… missed first 30 min
Longiudinal vs Transverse vibration of a linear molecule:
diagrams here
These are independent and can be solved separately
- 3 variables but only 2 longitudinal modes
figure here
We can eliminate translation by requiring the center-of-mass to be stationary during vibration
mx1+Mx2+mx3=0
x2=−Mm(x1+x3)
T=21mx˙12+21Mx˙22+21mx˙32
⋯=21m(x˙12+x˙32)+21Mm2(x˙12+x˙32+2x˙1x˙3)
We can decouple the system by switching coordinates. We must eliminate the x˙1x˙3 term.
Generalized coordinates:
q1=x1+x3
q2=x3−x1
x3=21(q1+q2), x1=21(q1−q2), x2=−Mmq1
Find the kinetic energy of this system
T=21mx˙12+21Mx˙22+21mx˙32
=21m41(q˙1−q˙2)2+21MM2m2q˙12+21m41(q˙1+q˙2)2
=21m41(q˙12+q˙22−2q˙1q˙2)+21Mm2q˙12+21m41(q˙12++q˙22+2q˙1q˙2)
Our coupling term cancels out. Kinetic energy finally given by
T=41mq˙22+4MmM+2m2q˙12
Finding potential:
u=21κ1(x2−x1)2+21κ1(x3−x2)2
=21κ1(x22+x12−2x1x2)+21κ1(x32+x22−2x2x3)
=21κ1(M2m2q12+41(q12+q22−q1q2)+2(21)(q1−q2)Mmq1)…
+21κ1(41(q12+q22+2q1q2)+M2m2q12221(q1+q2)Mmq1)
=κ1M2m2q12+41κ1(q12+q22)+κ1q12Mm
41κ1q22+κ1q12[4m24m2+4m2m2+4m24mM]
=41κ1q22+κ1q12[4m24m2+4mM+M2]
u=(2M2m+M)2κ1q12+41κ1q22
k∑(Ajk−ω2mjk)qk=0
Ajk=∂qj∂qk∂2u
qk(t)=qkei(ωt−δ)
A11=∂q12∂2u=2(2m2m+M)κ1
A22=∂q22∂2u=21κ1
A12=A21=0
T=21jk∑mjkq˙jq˙k
21m11q˙12=4mmM+2m2q˙12
m11=2mmM+2m2
21m22q˙22=41mq˙22
m22=2m
m12=m21=0
Ajk=[2(2m2m+M)2κ10021κ1]
mjk=[2mmM+2m2002m]
We have Ajk and mjk matrices.
det[21(m2m+M)κ1−ω22mmM+2m20021κ1−2ω2m]=0
ω12=21(m2m+M)2κ1m(2m+M)2M
ω12=mM2m+Mκ1
ω22=mκ1
Tensor is diagonalized which means that q1 and q2 are my normal coordinates.
q1=a11η1+a1η2
q2=a21η1+a22η2
[A11−ω12m1100A22−ω12m22][a11a22]=[00]
0a11+a21=0
0a11+[ ]a21=0
a21=0
a11=free var.
[10]
Transverse Vibrations:
figure here
m(y1+y3)+My2=0
y2=−Mm(y1+y3)
We will assume small oscillations, meaning that α is a small angle therefore
α=bΔy=b(y1−y2)+(y3−y2)
y1=y3
and substitute y2
α=bM2y1(2m+M)
T=21m(y˙12+y˙32)+21My22
T=Mm(2m+M)y˙12
T=4(2m+M)mMb2α˙2
u=21κ2(bα)2
ω32=mM2(2m+M)κ2
From the first and third normal modes EM radiation is detected because the electrical dipole moving.
2nd no radiation b/c no dipole
The Loaded Spring (12.9)
- n masses separated by distance d in equilibrium
- masses m are connected by springs or elastic strings
- Total length of string L=(n+1)d and fixed at both ends
figure here
Want to treat small transverse oscillations about equlibrium
consider particles:
j−1,j,j+1
displaced vertically
The force on the jth particle (considering only nearest neighbors)
graph here