… missed first 30 min

Longiudinal vs Transverse vibration of a linear molecule:

diagrams here

These are independent and can be solved separately

  • 3 variables but only 2 longitudinal modes

figure here

We can eliminate translation by requiring the center-of-mass to be stationary during vibration

We can decouple the system by switching coordinates. We must eliminate the term.

Generalized coordinates:

Find the kinetic energy of this system

Our coupling term cancels out. Kinetic energy finally given by

Finding potential:

We have and matrices.

Tensor is diagonalized which means that and are my normal coordinates.

Transverse Vibrations:

figure here

We will assume small oscillations, meaning that is a small angle therefore

and substitute

From the first and third normal modes EM radiation is detected because the electrical dipole moving. 2nd no radiation b/c no dipole

The Loaded Spring (12.9)

  • n masses separated by distance d in equilibrium
  • masses m are connected by springs or elastic strings
  • Total length of string and fixed at both ends

figure here

Want to treat small transverse oscillations about equlibrium

consider particles:

displaced vertically

The force on the particle (considering only nearest neighbors)

graph here